I use photoshop 7 and i found the dds plugin at Nvidia . . However after a quick search it seems that there is no plugin for your version. You might have to save your files as a different format then convert them.
I did some research on the plug-in a while back, and found that it has been discontinued. It hasn’t been updated since, I believe, CS2, and at that point there was no official 64-bit version of Photoshop. If you are willing to use the 32-bit version of Photoshop it does still work with that. I’ll warn you however that it was never a very good plug-in to begin with, and is far buggier than going with either of the other two programs.
In the end though I have to agree with everyone else that it will really benefit you to simply use Paint.NET or GIMP. I use Paint.NET myself, but it really is a very simple editing program. GIMP is far more powerful, but at the same time is a good deal more complicated. Both are free, and here’s the links to it.